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12012-95-2
C6H10Cl2Pd2
Description
Allylpalladium(II) chloride dimer is a yellow powder with the formula [(η3-C3H5)PdCl]2. This compound is an important catalyst used in organic synthesis. It is one of the most widely used transition metal allyl complexes. Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.
Applications：
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.
[Pd(allyl)Cl]2 can be used as a catalyst:
For the silylation of organobromides.
To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides.
To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Specification
Product Name | Allylpalladium chloride dimer |
Other Name | Allylpalladium(II) chloride dimer |
CAS No. | 12012-95-2 |
Molecular Formula: | C6H10Cl2Pd2 |
Molecular Weight: | 365.89 |
Appearance | Yellow to green-yellow Crystals or Crystalline Powder |
Type | Organometallic catalysts; fine chemicals; precious metal catalysts; organic precious metals; palladium catalysts; |
Purity | 99%min |
| Allylpalladium(II) Chloride Dimer Chemical Properties | |
| Melting point | 120°C (dec.) |
| Storage temp | 2-8°C |
| Form | Crystals or Crystalline Powder |
| Color | Yellow to green-yellow |
| Sensitive | Air Sensitive |
| Safety Information | |
| Hazard Codes | Xi,Xn |
| Risk Statements | 36/37/38-40 |
| Safety Statements | 26-36-36/37 |
| WGK Germany | 3 |
| F | 1-10 |
FAQ
● Is Uyanchem a manufacturer or just a trading company?
Uyanchem is a professional manufacturer of OLED intermediates and fine chemicals. Market oriented, Driven by R&D, To meet customer needs as our purpose. Uyanchem has developed rapidly since its inception
● What is the Min Order Quantity of Allylpalladium chloride dimer CAS: 12012-95-2?
Different products have different MOQ, We can provide mass production supply from G to ton
● What is the price of Allylpalladium chloride dimer CAS: 12012-95-2?
Uyanchem is a famous Allylpalladium chloride dimer CAS: 12012-95-2 supplier and manufacturer in China, we can provide you with cost-effective Allylpalladium chloride dimer CAS: 12012-95-2.
● How long shall we wait for your reply?
We can guarantee to reply your inquiries of Allylpalladium chloride dimer CAS: 12012-95-2 in less than 24 hours in working days.
● What kinds of transportation types can you provide?
Our main transportation methods include air transportation, land transportation, and water transportation.
● What kinds of payment terms can you accept?
The most commonly used payment terms are T/T, L/C, D/P, D/A, etc.
● How long will I receive my good?
Uyanchem has its own R&D laboratory and EDC warehouse in Shanghai when your purchase order has been confirmed, inventory products will deliver within 1 week .
Description
Allylpalladium(II) chloride dimer is a yellow powder with the formula [(η3-C3H5)PdCl]2. This compound is an important catalyst used in organic synthesis. It is one of the most widely used transition metal allyl complexes. Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.
Applications：
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.
[Pd(allyl)Cl]2 can be used as a catalyst:
For the silylation of organobromides.
To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides.
To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Specification
Product Name | Allylpalladium chloride dimer |
Other Name | Allylpalladium(II) chloride dimer |
CAS No. | 12012-95-2 |
Molecular Formula: | C6H10Cl2Pd2 |
Molecular Weight: | 365.89 |
Appearance | Yellow to green-yellow Crystals or Crystalline Powder |
Type | Organometallic catalysts; fine chemicals; precious metal catalysts; organic precious metals; palladium catalysts; |
Purity | 99%min |
| Allylpalladium(II) Chloride Dimer Chemical Properties | |
| Melting point | 120°C (dec.) |
| Storage temp | 2-8°C |
| Form | Crystals or Crystalline Powder |
| Color | Yellow to green-yellow |
| Sensitive | Air Sensitive |
| Safety Information | |
| Hazard Codes | Xi,Xn |
| Risk Statements | 36/37/38-40 |
| Safety Statements | 26-36-36/37 |
| WGK Germany | 3 |
| F | 1-10 |
FAQ
● Is Uyanchem a manufacturer or just a trading company?
Uyanchem is a professional manufacturer of OLED intermediates and fine chemicals. Market oriented, Driven by R&D, To meet customer needs as our purpose. Uyanchem has developed rapidly since its inception
● What is the Min Order Quantity of Allylpalladium chloride dimer CAS: 12012-95-2?
Different products have different MOQ, We can provide mass production supply from G to ton
● What is the price of Allylpalladium chloride dimer CAS: 12012-95-2?
Uyanchem is a famous Allylpalladium chloride dimer CAS: 12012-95-2 supplier and manufacturer in China, we can provide you with cost-effective Allylpalladium chloride dimer CAS: 12012-95-2.
● How long shall we wait for your reply?
We can guarantee to reply your inquiries of Allylpalladium chloride dimer CAS: 12012-95-2 in less than 24 hours in working days.
● What kinds of transportation types can you provide?
Our main transportation methods include air transportation, land transportation, and water transportation.
● What kinds of payment terms can you accept?
The most commonly used payment terms are T/T, L/C, D/P, D/A, etc.
● How long will I receive my good?
Uyanchem has its own R&D laboratory and EDC warehouse in Shanghai when your purchase order has been confirmed, inventory products will deliver within 1 week .
