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15243-33-1
C12O12Ru3
Description
The main application areas of triruthenium dodecacarbonyl are as follows:
1. As a catalyst for the [3+2+1] carbonyl cycloaddition reaction of silyl acetylene compounds and α, β-unsaturated ketones to obtain α-pyrone in high yield.
2. The precursor of carbonyl cluster compound and hydrogen transfer catalyst.
3. Used in the reductive carbonylation reaction of aromatic nitro compounds to generate carbamate.
4. The phosphine-stabilized carbonyl cluster compound has been attached to the oxide support.
5. It is used to obtain improved catalytic effect in the allyl amination reaction of unactivated olefins by aromatic nitro compounds.
Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.
Specification
Product Name | Triruthenium dodecacarbonyl |
Other Name | Ru3(CO)12;TrirutheniuMdodecacarbonyl99%;Trirutheniumdodecarbonyl(DCR);pentaoxonium;Ruthenium,dodecacarbonyltri-,triangulo;Ruthenium,dodecacarbonyltri-;DODECACARBONYLTRIRUTHENIUM |
CAS No. | 15243-33-1 |
Molecular Formula: | C12O12Ru3 |
Molecular Weight: | 639.33 |
Appearance | Orange powder |
Type | Inorganic chemicals; chemical reagents; precious metal catalysts; fine chemicals; precious metal compounds; |
Purity | 99%min |
Ruthenium carbonyl Chemical Properties
| Melting point | 150 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. |
| form | crystal |
| color | orange |
| CAS DataBase Reference | 15243-33-1(CAS DataBase Reference) |
| EPA Substance Registry System | Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1) |
Ruthenium carbonyl Safety Information
| Hazard Codes | F,Xn |
| Risk Statements | 11-20-2017/11/20 |
| Safety Statements | 24/25 |
| RIDADR | 1325 |
| WGK Germany | 3 |
| TSCA | Yes |
| PackingGroup | II |
Ruthenium carbonyl Usage And Synthesis
| Description | Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds. |
| Chemical Properties | The substance appears as orange plates or powder and is soluble in non-polar organic solvents. |
| Uses | Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF). |
FAQ
● Is Uyanchem a manufacturer or just a trading company?
Uyanchem is a professional manufacturer of OLED intermediates and fine chemicals. Market oriented, Driven by R&D, To meet customer needs as our purpose. Uyanchem has developed rapidly since its inception
● What is the Min Order Quantity of Triruthenium dodecacarbonyl CAS: 15243-33-1?
Different products have different MOQ, We can provide mass production supply from G to ton
● What is the price of Triruthenium dodecacarbonyl CAS: 15243-33-1?
Uyanchem is a famous Triruthenium dodecacarbonyl CAS: 15243-33-1 supplier and manufacturer in China, we can provide you with cost-effective Triruthenium dodecacarbonyl CAS: 15243-33-1.
● How long shall we wait for your reply?
We can guarantee to reply your inquiries of Triruthenium dodecacarbonyl CAS: 15243-33-1 in less than 24 hours in working days.
● What kinds of transportation types can you provide?
Our main transportation methods include air transportation, land transportation, and water transportation.
● What kinds of payment terms can you accept?
The most commonly used payment terms are T/T, L/C, D/P, D/A, etc.
● How long will I receive my good?
Uyanchem has its own R&D laboratory and EDC warehouse in Shanghai when your purchase order has been confirmed, inventory products will deliver within 1 week .
Description
The main application areas of triruthenium dodecacarbonyl are as follows:
1. As a catalyst for the [3+2+1] carbonyl cycloaddition reaction of silyl acetylene compounds and α, β-unsaturated ketones to obtain α-pyrone in high yield.
2. The precursor of carbonyl cluster compound and hydrogen transfer catalyst.
3. Used in the reductive carbonylation reaction of aromatic nitro compounds to generate carbamate.
4. The phosphine-stabilized carbonyl cluster compound has been attached to the oxide support.
5. It is used to obtain improved catalytic effect in the allyl amination reaction of unactivated olefins by aromatic nitro compounds.
Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.
Specification
Product Name | Triruthenium dodecacarbonyl |
Other Name | Ru3(CO)12;TrirutheniuMdodecacarbonyl99%;Trirutheniumdodecarbonyl(DCR);pentaoxonium;Ruthenium,dodecacarbonyltri-,triangulo;Ruthenium,dodecacarbonyltri-;DODECACARBONYLTRIRUTHENIUM |
CAS No. | 15243-33-1 |
Molecular Formula: | C12O12Ru3 |
Molecular Weight: | 639.33 |
Appearance | Orange powder |
Type | Inorganic chemicals; chemical reagents; precious metal catalysts; fine chemicals; precious metal compounds; |
Purity | 99%min |
Ruthenium carbonyl Chemical Properties
| Melting point | 150 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. |
| form | crystal |
| color | orange |
| CAS DataBase Reference | 15243-33-1(CAS DataBase Reference) |
| EPA Substance Registry System | Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1) |
Ruthenium carbonyl Safety Information
| Hazard Codes | F,Xn |
| Risk Statements | 11-20-2017/11/20 |
| Safety Statements | 24/25 |
| RIDADR | 1325 |
| WGK Germany | 3 |
| TSCA | Yes |
| PackingGroup | II |
Ruthenium carbonyl Usage And Synthesis
| Description | Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds. |
| Chemical Properties | The substance appears as orange plates or powder and is soluble in non-polar organic solvents. |
| Uses | Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF). |
FAQ
● Is Uyanchem a manufacturer or just a trading company?
Uyanchem is a professional manufacturer of OLED intermediates and fine chemicals. Market oriented, Driven by R&D, To meet customer needs as our purpose. Uyanchem has developed rapidly since its inception
● What is the Min Order Quantity of Triruthenium dodecacarbonyl CAS: 15243-33-1?
Different products have different MOQ, We can provide mass production supply from G to ton
● What is the price of Triruthenium dodecacarbonyl CAS: 15243-33-1?
Uyanchem is a famous Triruthenium dodecacarbonyl CAS: 15243-33-1 supplier and manufacturer in China, we can provide you with cost-effective Triruthenium dodecacarbonyl CAS: 15243-33-1.
● How long shall we wait for your reply?
We can guarantee to reply your inquiries of Triruthenium dodecacarbonyl CAS: 15243-33-1 in less than 24 hours in working days.
● What kinds of transportation types can you provide?
Our main transportation methods include air transportation, land transportation, and water transportation.
● What kinds of payment terms can you accept?
The most commonly used payment terms are T/T, L/C, D/P, D/A, etc.
● How long will I receive my good?
Uyanchem has its own R&D laboratory and EDC warehouse in Shanghai when your purchase order has been confirmed, inventory products will deliver within 1 week .
