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32005-36-0
C34H28O2Pd
Description
Bis(dibenzylideneacetone)palladium is normally a black or light brown powder solid. Bis(dibenzylideneacetone)palladium (Pd(dba)2) is an air-stable zero-valent palladium complex and an effective transition metal catalyst that can catalyze various organic reactions, such as cross-coupling reactions, Hydrogenation reaction, dipolar cycloaddition reaction, etc. In organic synthesis, bis(dibenzylideneacetone)palladium-catalyzed reactions generally exhibit high efficiency, high selectivity, and good functional group tolerance.
Specification
Product Name | Bis(dibenzylideneacetone)palladium |
Other Name | PD(DBA)2 |
CAS No. | 32005-36-0 |
Molecular Formula: | C34H28O2Pd |
Molecular Weight: | 575.01 |
Appearance | Light brown solid |
Type | Organometallic catalysts; fine chemicals; precious metal catalysts; organic precious metals; palladium catalysts; |
Purity | 99%min |
Bis(dibenzylideneacetone)palladium Chemical Properties
| Melting point | 150°C |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| solubility | Chloroform (Slightly) |
| form | Fine Powder |
| color | Red-brown to black |
| Water Solubility | insoluble |
| Sensitive | Air & Moisture Sensitive |
| Stability: | Hygroscopic |
| CAS DataBase Reference | 32005-36-0(CAS DataBase Reference) |
Bis(dibenzylideneacetone)palladium Safety Information
| Hazard Codes | Xi |
| Risk Statements | 36/38 |
| Safety Statements | 22-24/25-37/39-26 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
Bis(dibenzylideneacetone)palladium Usage And Synthesis
| Reaction |
|
| Chemical Properties | purple brown |
| Uses | Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction. |
| Uses | Application Guide for Palladium Catalyzed Cross-Coupling Reactions |
| Application | Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) was employed as catalyst in the following studies: Synthesis of isomeric 2-aryl-2,5-dihydrofurans, via Heck coupling of aryl bromides with alkenes using neopentyl phosphine ligands. Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand. Allylation of stabilized anions.Cross coupling of allyl, alkenyl and aryl halides with organostannanes. Cross coupling of vinyl halides with alkenyl zinc species.Carbonylation of alkenyl and aryl halides. Employed with cyclic thiourea ligands in an efficient aerobic oxidation of alcohols to aldehydes and ketones. |
| General Description | Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) is an air stable Pd0 complex. It is a reagent for the synthesis of allylic substituted cyclopentadienes. It is a homogeneous catalyst. It catalyzes the alkylation of allyl acetates by various nucleophiles under mild conditions. |
FAQ
● Is Uyanchem a manufacturer or just a trading company?
Uyanchem is a professional manufacturer of OLED intermediates and fine chemicals. Market oriented, Driven by R&D, To meet customer needs as our purpose. Uyanchem has developed rapidly since its inception
● What is the Min Order Quantity of Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0?
Different products have different MOQ, We can provide mass production supply from G to ton
● What is the price of Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0?
Uyanchem is a famous Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0 supplier and manufacturer in China, we can provide you with cost-effective Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0.
● How long shall we wait for your reply?
We can guarantee to reply your inquiries of Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0 in less than 24 hours in working days.
● What kinds of transportation types can you provide?
Our main transportation methods include air transportation, land transportation, and water transportation.
● What kinds of payment terms can you accept?
The most commonly used payment terms are T/T, L/C, D/P, D/A, etc.
● How long will I receive my good?
Uyanchem has its own R&D laboratory and EDC warehouse in Shanghai when your purchase order has been confirmed, inventory products will deliver within 1 week .
Description
Bis(dibenzylideneacetone)palladium is normally a black or light brown powder solid. Bis(dibenzylideneacetone)palladium (Pd(dba)2) is an air-stable zero-valent palladium complex and an effective transition metal catalyst that can catalyze various organic reactions, such as cross-coupling reactions, Hydrogenation reaction, dipolar cycloaddition reaction, etc. In organic synthesis, bis(dibenzylideneacetone)palladium-catalyzed reactions generally exhibit high efficiency, high selectivity, and good functional group tolerance.
Specification
Product Name | Bis(dibenzylideneacetone)palladium |
Other Name | PD(DBA)2 |
CAS No. | 32005-36-0 |
Molecular Formula: | C34H28O2Pd |
Molecular Weight: | 575.01 |
Appearance | Light brown solid |
Type | Organometallic catalysts; fine chemicals; precious metal catalysts; organic precious metals; palladium catalysts; |
Purity | 99%min |
Bis(dibenzylideneacetone)palladium Chemical Properties
| Melting point | 150°C |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| solubility | Chloroform (Slightly) |
| form | Fine Powder |
| color | Red-brown to black |
| Water Solubility | insoluble |
| Sensitive | Air & Moisture Sensitive |
| Stability: | Hygroscopic |
| CAS DataBase Reference | 32005-36-0(CAS DataBase Reference) |
Bis(dibenzylideneacetone)palladium Safety Information
| Hazard Codes | Xi |
| Risk Statements | 36/38 |
| Safety Statements | 22-24/25-37/39-26 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
Bis(dibenzylideneacetone)palladium Usage And Synthesis
| Reaction |
|
| Chemical Properties | purple brown |
| Uses | Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction. |
| Uses | Application Guide for Palladium Catalyzed Cross-Coupling Reactions |
| Application | Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) was employed as catalyst in the following studies: Synthesis of isomeric 2-aryl-2,5-dihydrofurans, via Heck coupling of aryl bromides with alkenes using neopentyl phosphine ligands. Heck reaction of benzyl trifluoroacetate and 2,3-dihydrofuran phosphoramidite ligand. Allylation of stabilized anions.Cross coupling of allyl, alkenyl and aryl halides with organostannanes. Cross coupling of vinyl halides with alkenyl zinc species.Carbonylation of alkenyl and aryl halides. Employed with cyclic thiourea ligands in an efficient aerobic oxidation of alcohols to aldehydes and ketones. |
| General Description | Bis(dibenzylideneacetone)palladium(0) (Pd(dba)2) is an air stable Pd0 complex. It is a reagent for the synthesis of allylic substituted cyclopentadienes. It is a homogeneous catalyst. It catalyzes the alkylation of allyl acetates by various nucleophiles under mild conditions. |
FAQ
● Is Uyanchem a manufacturer or just a trading company?
Uyanchem is a professional manufacturer of OLED intermediates and fine chemicals. Market oriented, Driven by R&D, To meet customer needs as our purpose. Uyanchem has developed rapidly since its inception
● What is the Min Order Quantity of Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0?
Different products have different MOQ, We can provide mass production supply from G to ton
● What is the price of Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0?
Uyanchem is a famous Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0 supplier and manufacturer in China, we can provide you with cost-effective Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0.
● How long shall we wait for your reply?
We can guarantee to reply your inquiries of Bis(dibenzylideneacetone)palladium PD(DBA)2 CAS: 32005-36-0 in less than 24 hours in working days.
● What kinds of transportation types can you provide?
Our main transportation methods include air transportation, land transportation, and water transportation.
● What kinds of payment terms can you accept?
The most commonly used payment terms are T/T, L/C, D/P, D/A, etc.
● How long will I receive my good?
Uyanchem has its own R&D laboratory and EDC warehouse in Shanghai when your purchase order has been confirmed, inventory products will deliver within 1 week .
